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Crotylboron-based synthesis of the polypropionate units of chaxamycins a/d, salinisporamycin, and rifamycin s

Academic Article
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Overview

related to degree

  • Chen, Ming, Ph.D. in Organic Chemistry, Scripps Research 2007 - 2012

authors

  • Chen, Ming
  • Roush, William

publication date

  • January 2013

journal

  • Journal of Organic Chemistry  Journal

abstract

  • Syntheses of the C(15)-C(27) fragments of chaxamycins A/D, rifamycin S, and the C(12)-C(24) fragment of salinisporamycin have been accomplished in 10 steps from commercially available starting materials. Three crotylboron reagents were utilized to construct the seven contiguous stereocenters in these fragments with excellent stereoselectivity.

subject areas

  • Anti-Bacterial Agents
  • Indicators and Reagents
  • Rifamycins
  • Stereoisomerism
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Identity

PubMed Central ID

  • PMC3465507

International Standard Serial Number (ISSN)

  • 0022-3263

Digital Object Identifier (DOI)

  • 10.1021/jo3008226

PubMed ID

  • 22703288
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Additional Document Info

start page

  • 3

end page

  • 8

volume

  • 78

issue

  • 1

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