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Allene-alkyne cross-coupling for stereoselective synthesis of substituted 1,4-dienes and cross-conjugated trienes

Academic Article
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Overview

authors

  • Shimp, H. L.
  • Hare, A.
  • McLaughlin, M.
  • Micalizio, Glenn

publication date

  • 2008

journal

  • Tetrahedron  Journal

abstract

  • Titanium-mediated cross-coupling of allenic alcohols with alkynes has been investigated. Divergent reaction pathways were discovered that provide either stereodefined 1,4-dienes or substituted cross-conjugated trienes. In short, allene substitution plays a critical role in the determination of reaction pathway.
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Identity

PubMed Central ID

  • PMC2577592

International Standard Serial Number (ISSN)

  • 0040-4020

Digital Object Identifier (DOI)

  • 10.1016/j.tet.2008.02.015

PubMed ID

  • 18985173
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Additional Document Info

start page

  • 3437

end page

  • 3445

volume

  • 64

issue

  • 16

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