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Synthesis of the C(1)-C(25) fragment of amphidinol 3: application of the double-allylboration reaction for synthesis of 1,5-diols

Academic Article
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Overview

authors

  • Flamme, E. M.
  • Roush, William

publication date

  • March 2005

journal

  • Organic Letters  Journal

abstract

  • [structure: see text] A synthesis of the C(1)-C(25) fragment of amphidinol 3 is described. The synthesis features two applications of double allylboration reaction methodology for the highly stereoselective synthesis of 1,5-diol units in the C(1)-C(15) segment.

subject areas

  • Alcohols
  • Alkenes
  • Animals
  • Boron Compounds
  • Catalysis
  • Dinoflagellida
  • Pyrans
  • Stereoisomerism
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Identity

International Standard Serial Number (ISSN)

  • 1523-7060

Digital Object Identifier (DOI)

  • 10.1021/ol050250q

PubMed ID

  • 15787519
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Additional Document Info

start page

  • 1411

end page

  • 1414

volume

  • 7

issue

  • 7

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