Scripps VIVO scripps research logo

  • Index
  • Log in
  • Home
  • People
  • Organizations
  • Research
  • Events
Search form
As of April 1st VIVO Scientific Profiles will no longer updated for faculty, and the link to VIVO will be removed from the library website. Faculty profile pages will continue to be updated via Interfolio. VIVO will continue being used behind the scenes to update graduate student profiles. Please contact helplib@scripps.edu if you have questions.
How to download citations from VIVO | Alternative profile options

Intramolecular Diels-Alder reactions of siloxacyclopentene constrained trienes

Academic Article
uri icon
  • Overview
  • Identity
  • Additional Document Info
  • View All
scroll to property group menus

Overview

related to degree

  • Halvorsen, Geoff, Ph.D. in Chemistry, Scripps Research , Transferred from University of Michigan 2005 - 2012

authors

  • Halvorsen, Geoff
  • Roush, William

publication date

  • May 2007

journal

  • Organic Letters  Journal

abstract

  • The synthesis of siloxacyclopentene-constrained trienes 7 and 10 and studies of their IMDA cycloadditions are described. The use of appropriately chosen thermal or Lewis acid conditions allows for cycloadducts 3-6 to be obtained with high levels of diastereoselectivity. These adducts possess trans-relationships between the hydroxyl group and the adjacent ring fusion proton, a stereochemical relationship not previously attainable in IMDA reactions.

subject areas

  • Cyclopentanes
  • Molecular Structure
  • Siloxanes
scroll to property group menus

Identity

PubMed Central ID

  • PMC2504012

International Standard Serial Number (ISSN)

  • 1523-7060

Digital Object Identifier (DOI)

  • 10.1021/ol070858u

PubMed ID

  • 17480094
scroll to property group menus

Additional Document Info

start page

  • 2243

end page

  • 2246

volume

  • 9

issue

  • 11

©2022 The Scripps Research Institute | Terms of Use | Powered by VIVO

  • About
  • Contact Us
  • Support