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Diastereoselective dieckmann condensation suitable for introduction of the duocarmycin A C6 center - development of a divergent strategy for the total synthesis of duocarmycins A and SA

Academic Article
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Overview

authors

  • Boger, Dale
  • Nishi, T.

publication date

  • January 1995

journal

  • Bioorganic & Medicinal Chemistry  Journal

abstract

  • The development of a divergent approach to the introduction of the C-ring of the duocarmycin A and SA alkylation subunits is detailed and includes the development of a diastereoselective Dieckmann condensation suitable for introduction of the duocarmycin A C6 center with control of its relative and natural R absolute configuration.

subject areas

  • Antibiotics, Antineoplastic
  • Carbon
  • Indoles
  • Molecular Structure
  • Pyrroles
  • Pyrrolidinones
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Identity

International Standard Serial Number (ISSN)

  • 0968-0896

Digital Object Identifier (DOI)

  • 10.1016/0968-0896(94)00147-u

PubMed ID

  • 8612048
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Additional Document Info

start page

  • 67

end page

  • 77

volume

  • 3

issue

  • 1

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