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Pd(0)/PR(3)-catalzed intermolecular arylation of sp(3) C-H bonds

Academic Article
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Overview

related to degree

  • Engle, Keary M., Ph.D. in Chemistry, Scripps Research 2008 - 2013
  • Wasa, Masayuki, Ph.D. in Chemistry, Scripps Research 2007 - 2012

authors

  • Wasa, Masayuki
  • Engle, Keary M.
  • Yu, Jin-Quan

publication date

  • July 2009

journal

  • Journal of the American Chemical Society  Journal

abstract

  • Pd(0)-catalyzed intermolecular arylation of sp(3) C-H bonds has been achieved using PR(3)/ArI. This protocol can be used to arylate a variety of aliphatic carboxylic acid derivatives, including a number of bioactive drug molecules. The use of fluorinated aryl iodides also allows for the introduction of fluorine into a molecule of interest.

subject areas

  • Amides
  • Catalysis
  • Ligands
  • Molecular Structure
  • Organometallic Compounds
  • Palladium
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Identity

PubMed Central ID

  • PMC2727875

International Standard Serial Number (ISSN)

  • 0002-7863

Digital Object Identifier (DOI)

  • 10.1021/ja903573p

PubMed ID

  • 19580277
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Additional Document Info

start page

  • 9886

end page

  • 9887

volume

  • 131

issue

  • 29

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