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Total synthesis of (+)-superstolide A

Academic Article
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Overview

authors

  • Tortosa, M.
  • Yakelis, N. A.
  • Roush, William

publication date

  • March 2008

journal

  • Journal of the American Chemical Society  Journal

abstract

  • A convergent and highly stereocontrolled synthesis of +-superstolide A (1) has been accomplished. Key steps of this synthesis include the intramolecular Suzuki reaction of 26 and the highly diastereoselective transannular Diels-Alder cyclization of macrocyclic octaene 3.

subject areas

  • Cyclization
  • Cytotoxins
  • Macrolides
  • Molecular Conformation
  • Stereoisomerism
  • Tetrahydronaphthalenes
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Identity

International Standard Serial Number (ISSN)

  • 0002-7863

Digital Object Identifier (DOI)

  • 10.1021/ja710238h

PubMed ID

  • 18254629
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Additional Document Info

start page

  • 2722

end page

  • 2723

volume

  • 130

issue

  • 9

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