Supramolecular isomerism in caviplexes

Academic Article

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• Research
• Identity
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Overview

authors

• Ma, S. H.
• Rudkevich, D. M.
• Rebek Jr., Julius

publication date

• 1999

journal

• Angewandte Chemie-International Edition  Journal

abstract

• Stereoisomeric complexes of an open-ended cavitand and its guest molecules (shown schematically) were detected, and complexes within caviplexes were introduced. Some control can be exerted on the stereoisomerism through methylation of the guest. The symbols "0" and "1" represent different ends of the guest molecule.

Research

keywords

• cavitands
• encapsulation
• hydrogen bonds
• stereoisomerism

Identity

International Standard Serial Number (ISSN)

• 1433-7851

Digital Object Identifier (DOI)

• 10.1002/(sici)1521-3773(19990903)38:17<2600::aid-anie2600>3.0.co;2-t

PubMed ID

• 10508352

Additional Document Info

start page

• 2600

end page

• 2602

volume

• 38

issue

• 17