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Cysteine-derived organocatalyst in a highly enantioselective intramolecular Michael reaction

Academic Article
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Overview

authors

  • Hayashi, Y.
  • Gotoh, Hiroaki
  • Tamura, T.
  • Yamaguchi, H.
  • Masui, R.
  • Shoji, M.

publication date

  • November 2005

journal

  • Journal of the American Chemical Society  Journal

abstract

  • Asymmetric intramolecular Michael reaction catalyzed by an organocatalyst derived from cysteine has been developed for the synthesis of chiral bicyclo[4.3.0]nonene and cis-disubstituted cyclopentane skeletons with a creation of three or two contiguous chiral centers in good yield with high diastereo- and excellent enantioselectivities.

subject areas

  • Catalysis
  • Cysteine
  • Molecular Structure
  • Stereoisomerism
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Identity

International Standard Serial Number (ISSN)

  • 0002-7863

Digital Object Identifier (DOI)

  • 10.1021/ja055740s

PubMed ID

  • 16287281
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Additional Document Info

start page

  • 16028

end page

  • 16029

volume

  • 127

issue

  • 46

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