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Mechanism and Stereoselectivity of Directed C(sp(3))-H Activation and Arylation Catalyzed by Pd(II) with Pyridine Ligand and Trifluoroacetate: A Computational Study

Academic Article
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Overview

authors

  • Jiang, J.
  • Yu, Jin-Quan
  • Morokuma, K.

publication date

  • June 2015

journal

  • ACS Catalysis  Journal
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Research

keywords

  • C(sp(2))-H activation
  • C(sp(3))-H activation
  • agostic interaction
  • diastereoselectivity
  • out-of-plane H-abstraction
  • unconventional CMD (or AMLA)
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Identity

International Standard Serial Number (ISSN)

  • 2155-5435

Digital Object Identifier (DOI)

  • 10.1021/cs501626n
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Additional Document Info

start page

  • 3648

end page

  • 3661

volume

  • 5

issue

  • 6

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