related to degree

• Crossley, Steven, Ph.D. in Biology, Scripps Research 2013 - 2018

authors

• Crossley, Steven
• Barabe, F.
• Shenvi, Ryan

publication date

• 2014

journal

• Journal of the American Chemical Society  Journal

abstract

• Catalytic amounts of Co(Sal(tBu,tBu))Cl and organosilane irreversibly isomerize terminal alkenes by one position. The same catalysts effect cycloisomerization of dienes and retrocycloisomerization of strained rings. Strong Lewis bases like amines and imidazoles, and labile functionalities like epoxides, are tolerated.

subject areas

• Alkenes
• Catalysis
• Cobalt
• Molecular Conformation
• Organometallic Compounds
• Silanes
• Stereoisomerism

PubMed Central ID

• PMC4277770

International Standard Serial Number (ISSN)

• 0002-7863

Digital Object Identifier (DOI)

• 10.1021/ja5105602

PubMed ID

• 25398144

start page

• 16788

end page

• 16791

volume

• 136

issue

• 48