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Silanes

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  • A convergent stereoselective synthesis of quinolizidines and indolizidines: Chemoselective coupling of 2-hydroxymethyl-substituted allylic silanes with imines  Academic Article
  • Applications of chiral allylmetallating agents toward the synthesis of oxygen heterocycles  Academic Article
  • Catalytic enantioselective amination of enolsilanes using C-2-symmetric copper(II) complexes as chiral Lewis acids  Academic Article
  • Copper-catalyzed Hiyama coupling of (hetero)aryltriethoxysilanes with (hetero)aryl iodides  Academic Article
  • Cu-catalyzed asymmetric conjugate additions of dialkyl- and diarylzinc reagents to acyclic beta-silyl-alpha,beta-unsaturated ketones. Synthesis of allylsilanes in high diastereo- and enantiomeric purity  Academic Article
  • Efficient protiodesilylation of unactivated C(sp3)-SiMe2Ph bonds using tetrabutylammonium fluoride  Academic Article
  • Enantio- and diastereoselective synthesis of cyclic beta-hydroxy allylsilanes via sequential aldehyde gamma-silylallylboration and ring-closing metathesis reactions  Academic Article
  • Enantio- and diastereoselective synthesis of syn-beta-hydroxyallylsilanes via a chiral (Z)-gamma-silylallylboronate  Academic Article
  • Enantioselective syntheses of syn- and anti-beta-hydroxyallyisilanes via allene hydroboration-aldehyde allylboration reactions  Academic Article
  • Enantioselective synthesis of (E)-δ-silyl-anti-homoallylic alcohols via an enantiodivergent hydroboration-crotylboration reaction of a racemic allenylsilane  Academic Article
  • Enantioselective synthesis of (Z)-1,2-anti-2,5-anti-triol monosilyl ethers using a cross-metathesis allylboration sequence  Academic Article
  • Enantioselective synthesis of allylsilanes bearing tertiary and quaternary Si-substituted carbons through Cu-catalyzed allylic Alkylations with alkylzinc and arylzinc reagents  Academic Article
  • Exceedingly fast copper(II)-promoted ortho C-H trifluoromethylation of arenes using TMSCF(3)  Academic Article
  • External compression-induced fracture patterning on the surface of poly(dimethylsiloxane) cubes and microspheres  Academic Article
  • Highly stereoselective and modular syntheses of 10-hydroxytrilobacin and three diastereomers via stereodivergent [3 + 2]-annulation reactions  Academic Article
  • Iridium-catalyzed enantioselective allylic substitution of enol silanes from vinylogous esters and amides  Academic Article
  • Iridium-catalyzed enantioselective allylic substitution of unstabilized enolates derived from α,β-unsaturated ketones  Academic Article
  • Ligand-enabled cross-coupling of C(sp(3))-H bonds with arylsilanes  Academic Article
  • New catalysts for the asymmetric hydrosilylation of ketones discovered by mass spectrometry screening  Academic Article
  • Olefin epoxidation with bis(trimethylsilyl) peroxide catalyzed by inorganic oxorhenium derivatives. Controlled release of hydrogen peroxide  Academic Article
  • Peptide amphiphile nanofibers template and catalyze silica nanotube formation  Academic Article
  • Regio- and stereoselectivity of diethylaluminum azide opening of trisubstituted epoxides and conversion of the 3 degrees azidohydrin adducts to isoprenoid aziridines  Academic Article
  • Ring-closing metathesis of allylsilanes as a flexible strategy toward cyclic terpenes. short syntheses of teucladiol, isoteucladiol, poitediol, and dactylol and an attempted synthesis of caryophyllene  Academic Article
  • Ring-closing metathesis of allylsilanes/electrophilic desilylation to prepare exo-methylidenecycloalkanes. Short syntheses of teucladiol and poitediol  Academic Article
  • Simple, chemoselective, catalytic olefin isomerization  Academic Article
  • Stereloselective synthesis of syn,syn- and syn,anti-1,3,5-triols via intramolecular hydrosilylation of substituted pent-3-en-1,5-diols  Academic Article
  • Stereochemistry of the allylation and crotylation reactions of alpha-methyl-beta-hydroxy aldehydes with allyl- and crotyltrifluorosilanes. Synthesis of anti, anti-dipropionate stereotriads and stereodivergent pathways for the reactions with 2,3-anti- and 2,3-syn-alpha-methyl-beta-hydroxy aldehydes  Academic Article
  • Stereocontrolled synthesis of syn-β-Hydroxy-α-amino acids by direct aldolization of pseudoephenamine glycinamide  Academic Article
  • Synthesis of (+)-bullatacin via the highly diastereoselective [3+2] annulation reaction of a racemic aldehyde and a nonracemic allylsilane  Academic Article
  • Synthesis of louisianin C  Academic Article
  • Total synthesis of amphidinolide E  Academic Article
  • Total synthesis of an immunomodulatory phosphoglycolipid from thermophilic bacteria  Academic Article
  • Total synthesis of asimicin via highly stereoselective [3 + 2] annulation reactions of substituted allylsilanes  Academic Article
  • Trifluoromethylation of allylsilanes under copper catalysis  Academic Article
  • Trifluoromethylation of allylsilanes under photoredox catalysis  Academic Article
  • Using antibodies to perturb the coordination sphere of a transition metal complex  Academic Article
  • [3 + 2]-annulation reactions of chiral allylsilanes and chiral aldehydes. Studies on the synthesis of bis-tetrahydrofuran substructures of annonaceous acetogenins  Academic Article
  • γ,δ,ε-C(sp(3))-H functionalization through directed radical H-abstraction  Academic Article

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