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Lactams

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  • 1,3-Diazepanes of natural product-like complexity from cyanamide-induced rearrangement of epoxy-delta-lactams  Academic Article
  • A small molecule that directs differentiation of human ESCs into the pancreatic lineage  Academic Article
  • A system for the continuous directed evolution of proteases rapidly reveals drug-resistance mutations  Academic Article
  • An alkoxide-directed intermolecular 2+2+1 annulation: A three-component coupling reaction for the synthesis of tetrasubstituted alpha,beta,-unsaturated gamma-lactams  Academic Article
  • Bifunctional acyltransferase/decarboxylase lnmk as the missing link for beta-alkylation in polyketide biosynthesis  Academic Article
  • C-S bond cleavage by a polyketide synthase domain  Academic Article
  • Chain initiation in the leinamycin-producing hybrid nonribosomal peptide/polyketide synthetase from streptomyces atroolivaceus s-140 - discrete, monofunctional adenylation enzyme and peptidyl carrier protein that directly load d-alanine  Academic Article
  • Characterization of the inmklm genes unveiling key intermediates for beta-alkylation in leinamycin biosynthesis  Academic Article
  • Clefts as receptor and enzyme analogues  Academic Article
  • Complex polycyclic lactams from pericyclic cascade reactions of Zincke aldehydes  Academic Article
  • Construction of highly functional α-amino nitriles via a novel multicomponent tandem organocatalytic reaction: a facile access to α-methylene γ-lactams  Academic Article
  • Convergent synthesis of stereodefined exo-alkylidene-gamma-lactams from beta-halo allylic alcohols  Academic Article
  • Enantioselective TADMAP-catalyzed carboxyl migration reactions for the synthesis of stereogenic quaternary carbon  Academic Article
  • Identification and localization of the gene cluster encoding biosynthesis of the antitumor macrolactam leinamycin in streptomyces atroolivaceus s-140  Academic Article
  • Identification of novel macrocyclic peptidase substrates via on-bead enzymatic cyclization  Academic Article
  • Iodine(V) reagents in organic synthesis. Part 3. New routes to heterocyclic compounds via o-iodoxybenzoic acid-mediated cyclizations: Generality, scope, and mechanism  Academic Article
  • Leinamycin E1 acting as an anticancer prodrug activated by reactive oxygen species  Academic Article
  • Leinamycin biosynthesis revealing unprecedented architectural complexity for a hybrid polyketide synthase and nonribosomal peptide synthetase  Academic Article
  • Ligand Enabled Pd(II)-Catalyzed gamma-C(sp(3))-H Lactamization of Native Amides  Academic Article
  • Macrolactamization of glycosylated peptide thioesters by the thioesterase domain of tyrocidine synthetase  Academic Article
  • N-(phenylthio)-epsilon-caprolactam: A new promoter for the activation of thioglycosides  Academic Article
  • One-pot synthesis of lactams using domino reactions: combination of Schmidt reaction with Sakurai and aldol reactions  Academic Article
  • Polyketide chain skipping mechanism in the biosynthesis of the hybrid nonribosomal peptide-polyketide antitumor antibiotic leinamycin in streptomyces atroolivaceus s-140  Academic Article
  • Reduced immunotoxicity and preservation of antibacterial activity in a releasable side-chain carbapenem antibiotic  Academic Article
  • Stereoselective synthesis of the disaccharide unit of incednine  Academic Article
  • Structure of the bifunctional acyltransferase/decarboxylase lnmk from the leinamycin biosynthetic pathway revealing novel activity for a double-hot-dog fold  Academic Article
  • Structure-based design, synthesis and evaluation of conformationally constrained cysteine protease inhibitors  Academic Article
  • Synthesis and evaluation of 8,4 '-dideshydroxy-leinamycin revealing new insights into the structure-activity relationship of the anticancer natural product leinamycin  Academic Article
  • Synthesis and evaluation of 8,4'-dideshydroxy-leinamycin revealing new insights into the structure-activity relationship of the anticancer natural product leinamycin  Academic Article
  • Synthesis of β-, γ-, and δ-Lactams via Pd(II)-catalyzed C−H activation reaction  Academic Article
  • The direct organocatalytic asymmetric mannich reaction: Unmodified aldehydes as nucleophiles  Academic Article
  • Type i polyketide synthase requiring a discrete acyltransferase for polyketide biosynthesis  Academic Article
  • γ,δ,ε-C(sp(3))-H functionalization through directed radical H-abstraction  Academic Article

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