Scripps VIVO scripps research logo

  • Index
  • Log in
  • Home
  • People
  • Organizations
  • Research
  • Events
Search form

Arylation of rhodium(II) azavinyl carbenes with boronic acids

Academic Article
uri icon
  • Overview
  • Identity
  • Additional Document Info
  • View All
scroll to property group menus

Overview

related to degree

  • Worrell, Brady, Ph.D. in Chemistry, Scripps Research 2008 - 2014

authors

  • Selander, N.
  • Worrell, Brady
  • Chuprakov, S.
  • Velaparthi, S.
  • Fokin, Valery

publication date

  • September 2012

journal

  • Journal of the American Chemical Society  Journal

abstract

  • A highly efficient and stereoselective arylation of in situ-generated azavinyl carbenes affording 2,2-diaryl enamines at ambient temperatures has been developed. These transition-metal carbenes are directly produced from readily available and stable 1-sulfonyl-1,2,3-triazoles in the presence of a rhodium carboxylate catalyst. In several cases, the enamines generated in this reaction can be cyclized into substituted indoles employing copper catalysis.

subject areas

  • Amines
  • Aza Compounds
  • Boronic Acids
  • Catalysis
  • Crystallography, X-Ray
  • Methane
  • Models, Molecular
  • Molecular Structure
  • Organometallic Compounds
  • Rhodium
  • Stereoisomerism
scroll to property group menus

Identity

PubMed Central ID

  • PMC3597238

International Standard Serial Number (ISSN)

  • 0002-7863

Digital Object Identifier (DOI)

  • 10.1021/ja3062453

PubMed ID

  • 22913576
scroll to property group menus

Additional Document Info

start page

  • 14670

end page

  • 14673

volume

  • 134

issue

  • 36

©2021 The Scripps Research Institute | Terms of Use | Powered by VIVO

  • About
  • Contact Us
  • Support