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Enantioselective synthesis of the C1-C11 fragment of tedanolide C

Academic Article
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Overview

authors

  • Geist, J. G.
  • Barth, R.
  • Roush, William

publication date

  • January 2013

journal

  • Organic Letters  Journal

abstract

  • A convergent synthesis of the protected C(1)-C(11) fragment 6 of the targeted enantiomer of tedanolide C is described. The key step of the synthesis is the Felkin-Ahn addition of vinyl iodide 7 to aldehyde 8 that proceeds in 80% yield with 4:1 diastereoselectivity.

subject areas

  • Animals
  • Macrolides
  • Molecular Structure
  • Porifera
  • Stereoisomerism
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Identity

PubMed Central ID

  • PMC3539184

International Standard Serial Number (ISSN)

  • 1523-7060

Digital Object Identifier (DOI)

  • 10.1021/ol303089w

PubMed ID

  • 23249423
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Additional Document Info

start page

  • 58

end page

  • 61

volume

  • 15

issue

  • 1

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