Reaction of carboxylic acids and isonitriles in small spaces

Academic Article

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Overview

authors

• Hou, J. L.
• Ajami, Dariush
• Rebek Jr., Julius

publication date

• June 2008

journal

• Journal of the American Chemical Society  Journal

abstract

• Reversible encapsulation complexes are applied to the reaction of isonitriles with carboxylic acids. Encapsulation facilitates these reactions by amplifying the concentration of reactants, arranging the acid and isonitrile in the appropriate orientations, isolating intermediates from bulk solution, and providing an organized solvent cage.

subject areas

• Carboxylic Acids
• Drug Compounding
• Models, Molecular
• Nitriles

Identity

International Standard Serial Number (ISSN)

• 0002-7863

Digital Object Identifier (DOI)

• 10.1021/ja802288k

PubMed ID

• 18507459

Additional Document Info

start page

• 7810

end page

• 7811

volume

• 130

issue

• 25