recent publications

• academic article

  • Chemler, S. R., Roush, W. R. Stereochemistry of the allylation and crotylation reactions of alpha-methyl-beta-hydroxy aldehydes with allyl- and crotyltrifluorosilanes. Synthesis of anti, anti-dipropionate stereotriads and stereodivergent pathways for the reactions with 2,3-anti- and 2,3-syn-alpha-methyl-beta-hydroxy aldehydes Journal of Organic Chemistry  2003 68:1319-1333  DOI:10.1021/jo0267908  PMID:12585871
  • Chemler, S. R., Roush, W. R. Stereochemically divergent pathways for the allylation and crotylation reactions of anti- and syn-beta-hydroxy-alpha-methyl aldehydes with allyl- and crotyltrifluorosilanes Tetrahedron Letters  1999 40:4643-4647  DOI:10.1016/s0040-4039(99)00730-3
  • Chemler, S. R., Coffey, D. S., Roush, W. R. An improved synthesis of the (E,Z)-dienoate precursor of (+)-damavaricin D via a vinylogous Horner-Wadsworth-Emmons reaction Tetrahedron Letters  1999 40:1269-1272  DOI:10.1016/s0040-4039(98)02638-0
  • Scheidt, K. A., Chen, H., Follows, B. C., Chemler, S. R., Coffey, D. S., Roush, W. R. Tris(dimethylamino)sulfonium difluorotrimethylsilicate, a mild reagent for the removal of silicon protecting groups Journal of Organic Chemistry  1998 63:6436-6437  DOI:10.1021/jo981215i
  • Chemler, S. R., Roush, W. R. Concerning the synthesis of the elusive anti,anti-dipropionate stereotriad via the crotylation of beta-hydroxy alpha-methyl aldehydes with (Z)-crotyltrifluorosilane. Application to the synthesis of the C(7)-C(16) segment of zincophorin Journal of Organic Chemistry  1998 63:3800-3801  DOI:10.1021/jo980387c