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Evolution of solid phase homochirality for a proteinogenic amino acid

Academic Article
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Overview

authors

  • Viedma, C.
  • Ortiz, J. E.
  • de Torres, T.
  • Izumi, T.
  • Blackmond, Donna

publication date

  • November 2008

journal

  • Journal of the American Chemical Society  Journal

abstract

  • The inexorable evolution of solid-phase single chirality is demonstrated for the first time for a proteinogenic amino acid. Enantioenrichment is observed both under attrition-enhanced conditions and without the aid of particle grinding. Differences in the form of the conversion profiles for the process under the two sets of conditions provide suggestions concerning the mechanism of the transformation.

subject areas

  • Amino Acids
  • Molecular Structure
  • Proteins
  • Stereoisomerism
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Identity

International Standard Serial Number (ISSN)

  • 0002-7863

Digital Object Identifier (DOI)

  • 10.1021/ja8074506

PubMed ID

  • 18954052
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Additional Document Info

start page

  • 15274

end page

  • 15275

volume

  • 130

issue

  • 46

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