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Catalysis by a synthetic receptor sealed at one end and functionalized at the other

Academic Article
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Overview

authors

  • Richeter, S.
  • Rebek Jr., Julius

publication date

  • December 2004

journal

  • Journal of the American Chemical Society  Journal

abstract

  • A deep cavitand bearing a zinc (II) salen wall catalyzes the hydrolysis of para-nitrophenylcholine carbonate. The closed end of the cavitand properly positions the carbonyl function of the substrate for activation by the metal center. Substrate specificity for acetylcholine derivatives results from simultaneous cation-pi interactions and a C=O- - -Zn coordination bond.

subject areas

  • Carbonates
  • Catalysis
  • Choline
  • Ethers, Cyclic
  • Kinetics
  • Magnetic Resonance Spectroscopy
  • Models, Molecular
  • Nitrobenzenes
  • Organometallic Compounds
  • Resorcinols
  • Zinc
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Identity

International Standard Serial Number (ISSN)

  • 0002-7863

Digital Object Identifier (DOI)

  • 10.1021/ja045167x

PubMed ID

  • 15600303
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Additional Document Info

start page

  • 16280

end page

  • 16281

volume

  • 126

issue

  • 50

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