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Ferrocene derivatives included in a water-soluble cavitand: Are they electroinactive?

Academic Article
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Overview

authors

  • Podkoscielny, D.
  • Hooley, R. J.
  • Rebek Jr., Julius
  • Kaifer, A. E.

publication date

  • July 2008

journal

  • Organic Letters  Journal

abstract

  • The formation in aqueous solution of kinetically stable inclusion complexes between a deep-cavity cavitand and several redox active ferrocene derivatives was demonstrated using (1)H NMR spectroscopy. The electrochemical kinetics of the inclusion complexes was strongly attenuated as compared to that observed with the free guests.

subject areas

  • Electrons
  • Ethers, Cyclic
  • Ferrous Compounds
  • Magnetic Resonance Spectroscopy
  • Models, Molecular
  • Molecular Structure
  • Resorcinols
  • Solubility
  • Water
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Identity

PubMed Central ID

  • PMC2654615

International Standard Serial Number (ISSN)

  • 1523-7060

Digital Object Identifier (DOI)

  • 10.1021/ol8010375

PubMed ID

  • 18537255
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Additional Document Info

start page

  • 2865

end page

  • 2868

volume

  • 10

issue

  • 13

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