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Highly efficient enantiospecific synthesis of imidazoline-containing amino acids using bis(triphenyl)oxodiphosphonium trifluoromethanesulfonate

Academic Article
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Overview

authors

  • You, S. L.
  • Kelly, Jeffery

publication date

  • May 2004

journal

  • Organic Letters  Journal

abstract

  • A highly efficient enantiospecific synthesis of imidazoline-based amino acids is reported from dipeptides composed of a C-terminal beta-amino-alpha-amino acid residue using bis(triphenyl) oxodiphosphonium trifluoromethanesulfonate. These imidazolines were easily converted to imidazoles and incorporated into macrolactam analogues of bistratamide H without loss of stereochemical integrity.

subject areas

  • Amino Acids
  • Imidazoles
  • Mesylates
  • Molecular Structure
  • Organophosphorus Compounds
  • Stereoisomerism
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Identity

International Standard Serial Number (ISSN)

  • 1523-7060

Digital Object Identifier (DOI)

  • 10.1021/ol049439c

PubMed ID

  • 15128266
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Additional Document Info

start page

  • 1681

end page

  • 1683

volume

  • 6

issue

  • 10

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