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Pd(II)-catalyzed enantioselective C-H olefination of diphenylacetic acids

Academic Article
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Overview

related to degree

  • Wang, Donghui, Ph.D., Scripps Research , transferred from Brandeis Univeristy 2007 - 2010

authors

  • Shi, B. F.
  • Zhang, Y. H.
  • Lam, J. K.
  • Wang, Donghui
  • Yu, Jin-Quan

publication date

  • January 2010

journal

  • Journal of the American Chemical Society  Journal

abstract

  • Pd(II)-catalyzed enantioselective C-H olefination of diphenylacetic acid substrates has been achieved through the use of monoprotected chiral amino acid ligands. The absolute configuration of the resulting olefinated products is consistent with that of a proposed C-H insertion intermediate.

subject areas

  • Aldehydes
  • Alkenes
  • Catalysis
  • Crystallography, X-Ray
  • Cyclization
  • Diphenylacetic Acids
  • Lactones
  • Models, Molecular
  • Molecular Structure
  • Organometallic Compounds
  • Palladium
  • Stereoisomerism
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Identity

PubMed Central ID

  • PMC2806936

International Standard Serial Number (ISSN)

  • 0002-7863

Digital Object Identifier (DOI)

  • 10.1021/ja909571z

PubMed ID

  • 20017549
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Additional Document Info

start page

  • 460

end page

  • 461

volume

  • 132

issue

  • 2

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