Scripps VIVO scripps research logo

  • Index
  • Log in
  • Home
  • People
  • Organizations
  • Research
  • Events
Search form

Electronic and steric effects in binding of deep cavitands

Academic Article
uri icon
  • Overview
  • Identity
  • Additional Document Info
  • View All
scroll to property group menus

Overview

authors

  • Hooley, R. J.
  • Shenoy, S. R.
  • Rebek Jr., Julius

publication date

  • December 2008

journal

  • Organic Letters  Journal

abstract

  • A deep, self-folding cavitand responds to minor electronic differences between suitably sized adamantane guests. Binding constants range from <0.5 to 4000 M(-1) for guests as similar as 1-bromoadamantane and 1-cyanoadamantane. The barriers to guest exchange also vary up to 3 kcal mol(-1).

subject areas

  • Adamantane
  • Electrons
  • Ethers, Cyclic
  • Models, Molecular
  • Molecular Conformation
  • Resorcinols
scroll to property group menus

Identity

PubMed Central ID

  • PMC2765558

International Standard Serial Number (ISSN)

  • 1523-7060

Digital Object Identifier (DOI)

  • 10.1021/ol8022775

PubMed ID

  • 18989966
scroll to property group menus

Additional Document Info

start page

  • 5397

end page

  • 5400

volume

  • 10

issue

  • 23

©2021 The Scripps Research Institute | Terms of Use | Powered by VIVO

  • About
  • Contact Us
  • Support