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Enantio- and diastereoselective synthesis of cyclic beta-hydroxy allylsilanes via sequential aldehyde gamma-silylallylboration and ring-closing metathesis reactions

Academic Article
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Overview

authors

  • Heo, J. N.
  • Micalizio, Glenn
  • Roush, William

publication date

  • May 2003

journal

  • Organic Letters  Journal

abstract

  • [reaction: see text] Highly enantioenriched cyclic allylsilanes are prepared via stereoselective gamma-silylallylboration reactions of beta- or gamma-unsaturated aldehydes followed by ring-closing metathesis.

subject areas

  • Aldehydes
  • Cyclization
  • Magnetic Resonance Spectroscopy
  • Silanes
  • Stereoisomerism
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Identity

International Standard Serial Number (ISSN)

  • 1523-7060

Digital Object Identifier (DOI)

  • 10.1021/ol034347t

PubMed ID

  • 12735754
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Additional Document Info

start page

  • 1693

end page

  • 1696

volume

  • 5

issue

  • 10

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