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An improved synthesis of alpha,beta-unsaturated nitrones relevant to the stephacidins and analogs thereof

Academic Article
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Overview

related to degree

  • Hafensteiner, Benjamin, Ph.D. in Chemistry, Scripps Research 2003 - 2008

authors

  • Hafensteiner, Benjamin
  • Escribano, M.
  • Petricci, E.
  • Baran, Phil

publication date

  • July 2009

journal

  • Bioorganic & Medicinal Chemistry Letters  Journal

abstract

  • A new method is reported for the synthesis of the alpha,beta-unsaturated nitrone moiety characteristic of the stephacidin/avrainvillamide family of bioactive prenylated indole alkaloids. Application to the synthesis of stephacidin analogs and a potential biological probe are showcased.

subject areas

  • Antineoplastic Agents
  • Indole Alkaloids
  • Indoles
  • Nitrogen Oxides
  • Oxidation-Reduction
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Research

keywords

  • Click-chemistry
  • Methodology
  • Oxidations
  • Synthesis
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Identity

PubMed Central ID

  • PMC2709696

International Standard Serial Number (ISSN)

  • 0960-894X

Digital Object Identifier (DOI)

  • 10.1016/j.bmcl.2009.04.045

PubMed ID

  • 19423345
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Additional Document Info

start page

  • 3808

end page

  • 3810

volume

  • 19

issue

  • 14

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