related to degree

• Patel, Paresma, Ph.D. in Organic Chemistry, Scripps Research 2005 - 2010

authors

• Patel, Paresma
• Boger, Dale

publication date

• 2010

journal

• Organic Letters  Journal

abstract

• The first intramolecular cycloaddition reactions of cyclopropenone ketals with tethered electron-deficient, electron-rich, and neutral 1-substituted dienes are reported, constituting inverse electron demand, normal, and neutral Diels-Alder reactions, that provide exclusively the exo [4 + 2] cycloaddition products without the intervention of [1 + 2], [3 + 2], or [3 + 4] cycloadducts in reactions whose courses do not depend on the reaction conditions, the diene activating substituent, or the nature of the tethering.

subject areas

• Cyclization
• Cyclopropanes
• Ethers, Cyclic
• Molecular Structure
• Polyenes
• Stereoisomerism

PubMed Central ID

• PMC2912946

International Standard Serial Number (ISSN)

• 1523-7060

Digital Object Identifier (DOI)

• 10.1021/ol101375a

PubMed ID

• 20614867

start page

• 3540

end page

• 3543

volume

• 12

issue

• 15