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Synthesis of precursors of the agalacto (exo) fragment of the quartromicins via an auxiliary-controlled exo-selective Diels-Alder reaction

Academic Article
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Overview

authors

  • Qi, J.
  • Roush, William

publication date

  • June 2006

journal

  • Organic Letters  Journal

abstract

  • [reaction: see text] A direct synthesis of the alpha-hydroxyaldehyde exo-5, a precursor of the exo-spirotetronate subunit of the quartromicins, was achieved through an exo-selective Lewis acid-catalyzed Diels-Alder reaction of dienophile 12a and diene 1.

subject areas

  • Catalysis
  • Furans
  • Molecular Structure
  • Spiro Compounds
  • Stereoisomerism
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Identity

PubMed Central ID

  • PMC2515626

International Standard Serial Number (ISSN)

  • 1523-7060

Digital Object Identifier (DOI)

  • 10.1021/ol0609208

PubMed ID

  • 16774259
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Additional Document Info

start page

  • 2795

end page

  • 2798

volume

  • 8

issue

  • 13

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