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Aliphatic imines in titanium-mediated reductive cross-coupling: Unique reactivity of ti(o-i-pr)(4)/n-buli

Academic Article
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Overview

authors

  • Tarselli, M. A.
  • Micalizio, Glenn

publication date

  • October 2009

journal

  • Organic Letters  Journal

abstract

  • A procedure for the coupling of aliphatic imines with allylic and allenic alkoxides is described. The success of these studies was enabled by a unique reactivity profile of Ti(IV) isopropoxide/n-BuLi compared to well-known Ti(IV) isopropoxide/RMgX systems.

subject areas

  • Alcohols
  • Imines
  • Organometallic Compounds
  • Oxidation-Reduction
  • Titanium
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Identity

PubMed Central ID

  • PMC2818175

International Standard Serial Number (ISSN)

  • 1523-7060

Digital Object Identifier (DOI)

  • 10.1021/ol901870n

PubMed ID

  • 19810765
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Additional Document Info

start page

  • 4596

end page

  • 4599

volume

  • 11

issue

  • 20

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