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Rhodium-catalyzed enantioselective cyclopropanation of olefins with N-sulfonyl 1,2,3-triazoles

Academic Article
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Overview

related to degree

  • Kwok, Sen Wai, Ph.D. in Organic Chemistry, Scripps Research 2005 - 2011

authors

  • Chuprakov, S.
  • Kwok, Sen Wai
  • Zhang, L.
  • Lercher, L.
  • Fokin, Valery

publication date

  • December 2009

journal

  • Journal of the American Chemical Society  Journal

abstract

  • N-Sulfonyl 1,2,3-triazoles readily form rhodium(II) azavinyl carbenes, which react with olefins to produce cyclopropanes with excellent diastereo- and enantioselectivity and in high yield.

subject areas

  • Alkenes
  • Aza Compounds
  • Catalysis
  • Cyclization
  • Cyclopropanes
  • Molecular Structure
  • Rhodium
  • Stereoisomerism
  • Sulfones
  • Triazoles
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Identity

PubMed Central ID

  • PMC2801057

International Standard Serial Number (ISSN)

  • 0002-7863

Digital Object Identifier (DOI)

  • 10.1021/ja908075u

PubMed ID

  • 19928917
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Additional Document Info

start page

  • 18034

end page

  • 18035

volume

  • 131

issue

  • 50

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