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Rhodium(II)-catalyzed asymmetric sulfur(VI) reduction of diazo sulfonylamidines

Academic Article
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Overview

authors

  • Selander, N.
  • Fokin, Valery

publication date

  • February 2012

journal

  • Journal of the American Chemical Society  Journal

abstract

  • Diazo sulfonylamidines readily undergo enantioselective oxygen transfer from sulfur to carbon atom in the presence of chiral rhodium(II) carboxylates resulting in chiral sulfinylamidines. This unusual asymmetric atom transfer "reduction" occurs rapidly under mild conditions, and sulfinylamidines are obtained in excellent yield.

subject areas

  • Amidines
  • Azo Compounds
  • Catalysis
  • Crystallography, X-Ray
  • Models, Molecular
  • Molecular Structure
  • Organometallic Compounds
  • Oxidation-Reduction
  • Rhodium
  • Stereoisomerism
  • Sulfinic Acids
  • Sulfur
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Identity

PubMed Central ID

  • PMC3627535

International Standard Serial Number (ISSN)

  • 0002-7863

Digital Object Identifier (DOI)

  • 10.1021/ja210180q

PubMed ID

  • 22233190
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Additional Document Info

start page

  • 2477

end page

  • 2480

volume

  • 134

issue

  • 5

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