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Diphenylprolinol silyl ether as catalyst of an asymmetric, catalytic, and direct Michael reaction of nitroalkanes with alpha,beta-unsaturated aldehydes

Academic Article
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Overview

authors

  • Gotoh, Hiroaki
  • Ishikawa, H.
  • Hayashi, Y.

publication date

  • December 2007

journal

  • Organic Letters  Journal

abstract

  • A catalytic enantioselective direct conjugate addition of nitroalkanes to alpha,beta-unsaturated aldehydes using diphenylprolinol silyl ether as an organocatalyst has been developed. Using this methodology as a key step, short syntheses of therapeutically useful compounds have also been accomplished.
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Identity

International Standard Serial Number (ISSN)

  • 1523-7060

Digital Object Identifier (DOI)

  • 10.1021/ol702545z

PubMed ID

  • 17997567
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Additional Document Info

start page

  • 5307

end page

  • 5309

volume

  • 9

issue

  • 25

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