Diarylprolinol silyl ether as catalyst of an exo-selective, enantioselective Diels-Alder reaction

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publication date

July 2007

journal

Organic Letters Journal

abstract

In combined use with CF3CO2H, 2-[bis(3,5-bis-trifluoromethylphenyl) triethylsiloxymethyl]pyrrolidine was found to be an effective organocatalyst of an exo-selective, enantioselective Diels-Alder reaction of alpha,beta-unsaturated aldehydes.