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Ligand-enabled cross-coupling of C(sp(3))-H bonds with arylsilanes

Academic Article
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Overview

related to degree

  • He, Jian, Ph.D. in Chemistry, Scripps Research 2011 - 2016

authors

  • He, Jian
  • Takise, R.
  • Fu, H.
  • Yu, Jin-Quan

publication date

  • April 2015

journal

  • Journal of the American Chemical Society  Journal

abstract

  • Pd(II)-catalyzed cross-coupling of C(sp(3))-H bonds with organosilicon coupling partners has been achieved for the first time. The use of a newly developed quinoline-based ligand is essential for the cross-coupling reactions to proceed.

subject areas

  • Carbon
  • Catalysis
  • Halogenation
  • Hydrogen
  • Ligands
  • Palladium
  • Silanes
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Identity

PubMed Central ID

  • PMC4432906

International Standard Serial Number (ISSN)

  • 0002-7863

Digital Object Identifier (DOI)

  • 10.1021/jacs.5b00890

PubMed ID

  • 25822198
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Additional Document Info

start page

  • 4618

end page

  • 4621

volume

  • 137

issue

  • 14

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