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Cu(OAc)2-catalyzed coupling of aromatic C-H bonds with arylboron reagents

Academic Article
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Overview

authors

  • Shang, M.
  • Sun, S. Z.
  • Dai, H. X.
  • Yu, Jin-Quan

publication date

  • November 2014

journal

  • Organic Letters  Journal

abstract

  • Cu-catalyzed coupling of aryl C-H bonds with arylboron reagents was accomplished using a readily removable directing group, which provides a useful method for the synthesis of biaryl compounds. The distinct transmetalation step in this Cu-catalyzed C-H coupling with aryl borons provides unique evidence for the formation of an aryl cupperate intermediate.

subject areas

  • Boron
  • Catalysis
  • Copper
  • Hydrogen Bonding
  • Indicators and Reagents
  • Molecular Structure
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Identity

International Standard Serial Number (ISSN)

  • 1523-7060

Digital Object Identifier (DOI)

  • 10.1021/ol5027377

PubMed ID

  • 25325402
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Additional Document Info

start page

  • 5666

end page

  • 5669

volume

  • 16

issue

  • 21

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