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Cu(II)-mediated ortho C-H alkynylation of (hetero)arenes with terminal alkynes

Academic Article
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Overview

authors

  • Shang, M.
  • Wang, H. L.
  • Sun, S. Z.
  • Dai, H. X.
  • Yu, Jin-Quan

publication date

  • 2014

journal

  • Journal of the American Chemical Society  Journal

abstract

  • Cu(II)-promoted ortho alkynylation of arenes and heteroarenes with terminal alkynes has been developed to prepare aryl alkynes. A variety of arenes and terminal alkynes bearing different substituents are compatible with this reaction, thus providing an alternative disconnection to Sonogashira coupling.

subject areas

  • Alkylation
  • Alkynes
  • Benzene Derivatives
  • Copper
  • Molecular Structure
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Identity

International Standard Serial Number (ISSN)

  • 0002-7863

Digital Object Identifier (DOI)

  • 10.1021/ja507704b

PubMed ID

  • 25087720
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Additional Document Info

start page

  • 11590

end page

  • 11593

volume

  • 136

issue

  • 33

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