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Ligand-enabled gamma-C-H olefination and carbonylation: construction of beta-quaternary carbon centers

Academic Article
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Overview

authors

  • Li, S.
  • Chen, G.
  • Feng, C. G.
  • Gong, W.
  • Yu, Jin-Quan

publication date

  • 2014

journal

  • Journal of the American Chemical Society  Journal

abstract

  • Monoselective γ-C-H olefination and carbonylation of aliphatic acids has been accomplished by using a combination of a quinoline-based ligand and a weakly coordinating amide directing group. The reaction provides a new route for constructing richly functionalized all-carbon quaternary carbon centers at the β-position of aliphatic acids.

subject areas

  • Alkenes
  • Carbon
  • Fatty Acids
  • Ligands
  • Molecular Structure
  • Quinolines
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Identity

PubMed Central ID

  • PMC4049142

International Standard Serial Number (ISSN)

  • 0002-7863

Digital Object Identifier (DOI)

  • 10.1021/ja501689j

PubMed ID

  • 24666182
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Additional Document Info

start page

  • 5267

end page

  • 5270

volume

  • 136

issue

  • 14

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