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Sarlah, David
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Sarlah, David

Graduate Student
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Positions

  • 2014 - Faculty Member, University of Illinois at Urbana-Champaign

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Publications

recent publications
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  • academic article

    • Hernandez, L. W., Sarlah, D. Empowering synthesis of complex natural products Chemistry-a European Journal  2019  DOI:10.1002/chem.201901808  PMID:31194262
    • Tang, C., Okumura, M., Zhu, Y., Hooper, A. R., Zhou, Y., Lee, Y. H., Sarlah, D. Palladium-catalyzed dearomative syn-1,4-carboamination with Grignard reagents Angewandte Chemie-International Edition  2019 58:10245-10249  DOI:10.1002/anie.201905021  PMID:31090252  PMCID:PMC6640109
    • Dennis, D. G., Okumura, M., Sarlah, D. Synthesis of (+/-)-idarubicinone via global functionalization of tetracene Journal of the American Chemical Society  2019 141:10193-10198  DOI:10.1021/jacs.9b05370  PMID:31244190
    • Bingham, T. W., Hernandez, L. W., Olson, D. G., Svec, R. L., Hergenrother, P. J., Sarlah, D. Enantioselective synthesis of isocarbostyril alkaloids and analogs using catalytic dearomative functionalization of benzene Journal of the American Chemical Society  2019 141:657-670  DOI:10.1021/jacs.8b12123  PMID:30520639  PMCID:PMC6488038
    • Wertjes, W. C., Okumura, M., Sarlah, D. Palladium-catalyzed dearomative syn-1,4-diamination Journal of the American Chemical Society  2019 141:163-167  DOI:10.1021/jacs.8b13030  PMID:30566338  PMCID:PMC6488036
    • Wertjes, W. C., Southgate, E. H., Sarlah, D. Recent advances in chemical dearomatization of nonactivated arenes Chemical Society Reviews  2018 47:7996-8017  DOI:10.1039/c8cs00389k  PMID:30073226
    • Hernandez, L. W., Klockner, U., Pospech, J., Hauss, L., Sarlah, D. Nickel-catalyzed dearomative trans-1,2-carboamination Journal of the American Chemical Society  2018 140:4503-4507  DOI:10.1021/jacs.8b01726  PMID:29544244  PMCID:PMC5971658
    • Okumura, M., Sarlah, D. Arenophile-mediated dearomative functionalization strategies Synlett  2018 29:845-855  DOI:10.1055/s-0036-1591940
    • Sarlah, D., Okumura, M., Shved, A. Palladium-catalyzed dearomative syn-1,4-carboamination Synlett  2018 29:A40-A43
    • Sarlah, D., Okumura, M., Shved, A. Palladium-catalyzed dearomative syn-1,4-carboamination Synthesis-Stuttgart  2018 50:A40-A43  DOI:10.1055/s-0036-1591457  PMID:29183109  PMCID:PMC5971112
    • Okumura, M., Shved, A. S., Sarlah, D. Palladium-catalyzed dearomative syn-1,4-carboamination Journal of the American Chemical Society  2017 139:17787-17790  DOI:10.1021/jacs.8b13030  PMID:29183109  PMCID:PMC5971112
    • Hernandez, L. W., Pospech, J., Klockner, U., Bingham, T. W., Sarlah, D. Synthesis of (+)-pancratistatins via catalytic desymmetrization of benzene Journal of the American Chemical Society  2017 139:15656-15659  DOI:10.1021/jacs.7b10351  PMID:29059521  PMCID:PMC5960067
    • Schafroth, M. A., Rummelt, S. M., Sarlah, D., Carreira, E. M. Enantioselective iridium-catalyzed allylic cyclizations Organic Letters  2017 19:3235-3238  DOI:10.1021/acs.orglett.7b01346  PMID:28573860
    • Southgate, E. H., Holycross, D. R., Sarlah, D. Total synthesis of lycoricidine and narciclasine by chemical dearomatization of bromobenzene Angewandte Chemie-International Edition  2017 56:15049-15052  DOI:10.1002/anie.201709712  PMID:29024240  PMCID:PMC5971115
    • Okumura, M., Huynh, S. M. N., Pospech, J., Sarlah, D. Arenophile-mediated dearomative reduction Angewandte Chemie-International Edition  2016 55:15910-15914  DOI:10.1002/anie.201609686  PMID:27879027  PMCID:PMC6043355
    • Southgate, E. H., Pospech, J., Fu, J., Holycross, D. R., Sarlah, D. Dearomative dihydroxylation with arenophiles Nature Chemistry  2016 8:922-928  DOI:10.1038/nchem.2594  PMID:27657867  PMCID:PMC5971114
    • Sarlah, D. Organic chemistry: No double bond left behind Nature  2016 531:453-454  PMID:27008963
    • Sarlah, D., Juranovic, A., Kozar, B., Rejc, L., Golobic, A., Petric, A. Synthesis of naphthalene-based push-pull molecules with a heteroaromatic electron acceptor Molecules  2016 21  DOI:10.3390/molecules21030267  PMID:26950099
    • Ungarean, C. N., Southgate, E. H., Sarlah, D. Enantioselective polyene cyclizations Organic & Biomolecular Chemistry  2016 14:5454-5467  DOI:10.1039/c6ob00375c  PMID:27143099
    • Hamilton, J. Y., Sarlah, D., Carreira, E. M. Iridium-catalyzed enantioselective allylic alkylation with functionalized organozinc bromides Angewandte Chemie-International Edition  2015 54:7644-7647  DOI:10.1002/anie.201501851  PMID:25969352
    • Shemet, A., Sarlah, D., Carreira, E. M. Stereochemical studies of the opening of chloro vinyl epoxides: cyclic chloronium ions as intermediates Organic Letters  2015 17:1878-1881  DOI:10.1021/acs.orglett.5b00558  PMID:25811099
    • Schafroth, M. A., Zuccarello, G., Krautwald, S., Sarlah, D., Carreira, E. M. Stereodivergent total synthesis of Δ9-tetrahydrocannabinols Angewandte Chemie - International Edition  2014 53:13898-13901  DOI:10.1002/anie.201408380  PMID:25303495
    • Hamilton, J. Y., Hauser, N., Sarlah, D., Carreira, E. M. Iridium-catalyzed enantioselective allyl-allylsilane cross-coupling Angewandte Chemie - International Edition  2014 53:10759-10762  DOI:10.1002/anie.201406077  PMID:25111443
    • Hamilton, J. Y., Sarlah, D., Carreira, E. M. Iridium-catalyzed enantioselective allyl-alkene coupling Journal of the American Chemical Society  2014 136:3006-3009  DOI:10.1021/ja412962w  PMID:24521052
    • Krautwald, S., Schafroth, M. A., Sarlah, D., Carreira, E. M. Stereodivergent α-allylation of linear aldehydes with dual iridium and amine catalysis Journal of the American Chemical Society  2014 136:3020-3023  DOI:10.1021/ja5003247  PMID:24506196
    • Lin, T. Y., Chin, C. R., Everitt, A. R., Clare, S., Perreira, J. M., Savidis, G., Aker, A. M., John, S. P., Sarlah, D., Carreira, E. M., Elledge, S. J., Kellam, P., et al. Amphotericin B increases influenza A virus infection by preventing IFITM3-mediated restriction Cell Reports  2013 5:895-908  DOI:10.1016/j.celrep.2013.10.033  PMID:24268777  PMCID:PMC3898084
    • Hamilton, J. Y., Sarlah, D., Carreira, E. M. Iridium-catalyzed enantioselective allylic alkynylation Angewandte Chemie - International Edition  2013 52:7532-7535  DOI:10.1002/anie.201302731  PMID:23712914
    • Krautwald, S., Sarlah, D., Schafroth, M. A., Carreira, E. M. Enantio- and diastereodivergent dual catalysis: α-allylation of branched aldehydes Science  2013 340:1065-1068  DOI:10.1126/science.1237068  PMID:23723229
    • Hamilton, J. Y., Sarlah, D., Carreira, E. M. Iridium-catalyzed enantioselective allylic vinylation Journal of the American Chemical Society  2013 135:994-997  DOI:10.1021/ja311422z  PMID:23256708
    • Schafroth, M. A., Sarlah, D., Krautwald, S., Carreira, E. M. Iridium-catalyzed enantioselective polyene cyclization Journal of the American Chemical Society  2012 134:20276-20278  DOI:10.1021/ja310386m  PMID:23193947
    • degree-related publication Nicolaou, K. C., Lu, M., Totokotsopoulos, S., Heretsch, P., Giguere, D., Sun, Y. P., Sarlah, D., Nguyen, T. H., Wolf, I. C., Smee, D. F., Day, C. W., Bopp, S., et al. Synthesis and biological evaluation of epidithio-, epitetrathio-, and bis-(methylthio)diketopiperazines: synthetic methodology, enantioselective total synthesis of epicoccin G, 8,8'-epi-ent-rostratin B, gliotoxin, gliotoxin G, emethallicin E, and haematocin and discovery of new antiviral and antimalarial agents Journal of the American Chemical Society  2012 134:17320-17332  DOI:10.1021/ja308429f  PMID:22978674  PMCID:PMC3490634
    • degree-related publication Nicolaou, K. C., Sun, Y. P., Sarlah, D., Zhan, W. Q., Wu, T. R. Bioinspired synthesis of hirsutellones A, B, and C Organic Letters  2011 13:5708-5710  DOI:10.1021/ol202239u  PMID:21913732  PMCID:PMC3207260
    • degree-related publication Nicolaou, K. C., Totokotsopoulos, S., Giguere, D., Sun, Y. P., Sarlah, D. Total synthesis of epicoccin G Journal of the American Chemical Society  2011 133:8150-8153  DOI:10.1021/ja2032635  PMID:21548595  PMCID:PMC3102137
    • degree-related publication Nicolaou, K. C., Sanchini, S., Sarlah, D., Lu, G., Wu, T. R., Nomura, D. K., Cravatt, B. F., Cubitt, B., de la Torre, J. C., Hessell, A. J., Burton, D. R. Design, synthesis, and biological evaluation of a biyouyanagin compound library Proceedings of the National Academy of Sciences of the United States of America  2011 108:6715-6720  DOI:10.1073/pnas.1015258108  PMID:21245351  PMCID:PMC3084107
    • degree-related publication Nicolaou, K. C., Sun, Y. P., Korman, H., Sarlah, D. Asymmetric total synthesis of cylindrocyclophanes A and F through cyclodimerization and a Ramberg-Bäcklund reaction Angewandte Chemie-International Edition  2010 49:5875-5878  DOI:10.1002/anie.201003500  PMID:20623817  PMCID:PMC3014728
    • degree-related publication Nicolaou, K. C., Sanchini, S., Wu, T. R., Sarlah, D. Total synthesis and structural revision of biyouyanagin B Chemistry-a European Journal  2010 16:7678-7682  DOI:10.1002/chem.201001474  PMID:20572192  PMCID:PMC3023179
    • degree-related publication Nicolaou, K. C., Reingruber, R., Sarlah, D., Brase, S. Enantioselective intramolecular Friedel−Crafts-type α-arylation of aldehydes Journal of the American Chemical Society  2009 131:2086-2087  DOI:10.1021/ja809405c  PMID:19173649
    • degree-related publication Nicolaou, K. C.*, Sarlah, D.*, Wu, T. R., Zhan, W. Q. Total synthesis of hirsutellone B Angewandte Chemie-International Edition  2009 48:6870-6874  DOI:10.1002/anie.200903382  PMID:19685548  PMCID:PMC2772144 (* = equal contribution)
    • degree-related publication Nicolaou, K. C., Wu, T. R., Sarlah, D., Shaw, D. M., Rowcliffe, E., Burton, D. R. Total synthesis, revised structure, and biological evaluation of biyouyanagin A and analogues thereof Journal of the American Chemical Society  2008 130:11114-11121  DOI:10.1021/ja802805c  PMID:18646750  PMCID:PMC2614900
    • Dai, M., Sarlah, D., Yu, M., Danishefsky, S. J., Jones, G. O., Houk, K. N. Highly selective Diels-Alder reactions of directly connected enyne dienophiles Journal of the American Chemical Society  2007 129:645-657  DOI:10.1021/ja065762u  PMID:17227028
    • degree-related publication Nicolaou, K. C.*, Sarlah, D.*, Shaw, D. M. Total synthesis and revised structure of biyouyanagin A Angewandte Chemie-International Edition  2007 46:4708-4711  DOI:10.1002/anie.200701552  PMID:17523208 (* = equal contribution)
    • degree-related publication Nicolaou, K. C., Pihko, P. M., Bernal, F., Frederick, M. O., Qian, W. Y., Uesaka, N., Diedrichs, N., Hinrichs, J., Koftis, T. V., Loizidou, E., Petrovic, G., Rodriquez, M., et al. Total synthesis and structural elucidation of azaspiracid-1. Construction of key building blocks for originally proposed structure Journal of the American Chemical Society  2006 128:2244-2257  DOI:10.1021/ja0547477  PMID:16478178
    • Zorko, M., Majerle, A., Sarlah, D., Keber, M. M., Mohar, B., Jerala, R. Combination of antimicrobial and endotoxin-neutralizing activities of novel oleoylamines Antimicrobial Agents and Chemotherapy  2005 49:2307-2313  DOI:10.1128/;aac.49.6.2307-2313.2005  PMID:15917526  PMCID:PMC1140490
    • Nicolaou, K. C., Bulger, P. G., Sarlah, D. Metathesis reactions in total synthesis Angewandte Chemie-International Edition  2005 44:4490-4527  DOI:10.1002/anie.200500369  PMID:16003791
    • Nicolaou, K. C., Bulger, P. G., Sarlah, D. Palladium-catalyzed cross-coupling reactions in total synthesis Angewandte Chemie-International Edition  2005 44:4442-4489  DOI:10.1002/anie.200500368  PMID:15991198
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Background

education and training

  • Ph.D. in Chemistry, Scripps Research 2006 - 2011
  • B.S. in Chemistry, University of Ljubljana 2006

advisee of

  • graduate advising relationship

    • Nicolaou, K.C., Ph.D.  candidacy, 2007 - 2011
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Contact

full name

  • David Sarlah

geographic location

  • Scripps California 
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Identity

ORCID iD

  • ORCID iD http://orcid.org/0000-0002-8736-8953

Scopus ID

  • 16680405500

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