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Liu, Zhen
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Liu, Zhen

Graduate Student
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Publications

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    • degree-related publication Liu, Z., Gao, Y., Zeng, T., Engle, K. M. Transition-metal-catalyzed 1,2-carboboration of alkenes: strategies, mechanisms, and stereocontrol Israel Journal of Chemistry  2020  DOI:10.1002/ijch.201900087
    • degree-related publication Liu, Z., Chen, J., Lu, H. X., Li, X., Gao, Y., Coombs, J. R., Goldfogel, M. J., Engle, K. M. Palladium(0)-catalyzed directed syn-1,2-carboboration and -silylation: alkene scope, applications in dearomatization, and stereocontrol by a chiral auxiliary Angewandte Chemie-International Edition  2019  DOI:10.1002/anie.201910304  PMID:31538388
    • degree-related publication Liu, Z., Li, X., Zeng, T., Engle, K. M. Directed, palladium(II)-catalyzed enantioselective anti-carboboration of alkenyl carbonyl compounds ACS Catalysis  2019 9:3260-3265  DOI:10.1021/acscatal.9b00181
    • degree-related publication Zeng, T., Liu, Z., Schmidt, M. A., Eastgate, M. D., Engle, K. M. Directed, palladium(II)-catalyzed intermolecular aminohydroxylation of alkenes using a mild oxidation system Organic Letters  2018 20:3853-3857  DOI:10.1021/acs.orglett.8b01440  PMID:29888604  PMCID:PMC6039249
    • degree-related publication Gao, D. W., Xiao, Y., Liu, M., Liu, Z., Karunananda, M. K., Chen, J. S., Engle, K. M. Catalytic, enantioselective synthesis of allenyl boronates ACS Catalysis  2018 8:3650-3654  DOI:10.1021/acscatal.8b00626
    • degree-related publication Liu, Z., Ni, H. Q., Zeng, T., Engle, K. M. Catalytic carbo- and aminoboration of alkenyl carbonyl compounds via five- and six-membered palladacycles Journal of the American Chemical Society  2018 140:3223-3227  DOI:10.1021/jacs.8b00881  PMID:29384373
    • degree-related publication Liu, Z., Wang, Y., Wang, Z., Zeng, T., Liu, P., Engle, K. M. Catalytic intermolecular carboamination of unactivated alkenes via directed aminopalladation Journal of the American Chemical Society  2017 139:11261-11270  DOI:10.1021/jacs.7b06520  PMID:28727452
    • degree-related publication Derosa, J., Cantu, A. L., Boulous, M. N., O'Duill, M. L., Turnbull, J. L., Liu, Z., De La Torre, D. M., Engle, K. M. Palladium(II)-catalyzed directed anti-hydrochlorination of unactivated alkynes with HCl Journal of the American Chemical Society  2017 139:5183-5193  DOI:10.1021/jacs.7b00892  PMID:28266849
    • Feng, S., Mo, F., Xia, Y., Liu, Z., Liu, Z., Zhang, Y., Wang, J. Rhodium(I)-Catalyzed C-C Bond Activation of Siloxyvinylcyclopropanes with Diazoesters Angewandte Chemie-International Edition  2016 55:15401-15405  DOI:10.1002/anie.201609642  PMID:27862772
    • degree-related publication Liu, Z., Zeng, T., Yang, K. S., Engle, K. M. β,γ-vicinal dicarbofunctionalization of alkenyl carbonyl compounds via directed nucleopalladation Journal of the American Chemical Society  2016 138:15122-15125  DOI:10.1021/jacs.6b09170  PMID:27779861
    • degree-related publication Yang, K. S., Gurak Jr., J. A., Liu, Z., Engle, K. M. Catalytic, regioselective hydrocarbofunctionalization of unactivated alkenes with diverse C-H nucleophiles Journal of the American Chemical Society  2016 138:14705-14712  DOI:10.1021/jacs.6b08850  PMID:27709911
    • degree-related publication Liu, Z., Derosa, J., Engle, K. M. Palladium(II)-catalyzed regioselective syn-hydroarylation of disubstituted alkynes using a removable directing group Journal of the American Chemical Society  2016 138:13076-13081  DOI:10.1021/jacs.6b08818  PMID:27602748
    • degree-related publication Gurak, J. A., Yang, K. S., Liu, Z., Engle, K. M. Directed, regiocontrolled hydroamination of unactivated alkenes via protodepalladation Journal of the American Chemical Society  2016 138:5805-5808  DOI:10.1021/jacs.6b02718  PMID:27093112
    • Liu, Z., Xia, Y., Feng, S., Zhang, Y., Wang, J. Rh(I)-Catalyzed coupling of 2-bromoethyl aryldiazoacetates with tertiary propargyl alcohols through carbene migratory insertion Organic Chemistry Frontiers  2016 3:1691-1698  DOI:10.1039/c6qo00453a
    • Xia, Y., Ge, R., Chen, L., Liu, Z., Xiao, Q., Zhang, Y., Wang, J. Palladium-catalyzed oxidative cross-coupling of conjugated enynones with organoboronic acids Journal of Organic Chemistry  2015 80:7856-7864  DOI:10.1021/acs.joc.5b01350  PMID:26219829
    • Xia, Y., Feng, S., Liu, Z., Zhang, Y., Wang, J. Rhodium(I)-catalyzed sequential C(sp)C(sp(3)) and C(sp(3))C(sp(3)) bond formation through migratory carbene insertion Angewandte Chemie-International Edition  2015 54:7891-7894  DOI:10.1002/anie.201503140  PMID:25982105
    • Xia, Y., Liu, Z., Feng, S., Ye, F., Zhang, Y., Wang, J. Rh(I)-catalyzed cross-coupling of α-diazoesters with arylsiloxanes Organic Letters  2015 17:956-959  DOI:10.1021/acs.orglett.5b00052  PMID:25671642
    • Xia, Y., Liu, Z., Feng, S., Zhang, Y., Wang, J. Ir(III)-catalyzed aromatic C-H bond functionalization via metal carbene migratory insertion Journal of Organic Chemistry  2015 80:223-236  DOI:10.1021/jo5023102  PMID:25437770
    • Xia, Y., Liu, Z., Ge, R., Xiao, Q., Zhang, Y., Wang, J. Pd-catalyzed cross-coupling of terminal alkynes with ene-yne-ketones: access to conjugated enynes via metal carbene migratory insertion Chemical Communications  2015 51:11233-11235  DOI:10.1039/c5cc03559g  PMID:26077197
    • Liu, Z., Xia, Y., Feng, S., Wang, S., Qiu, D., Zhang, Y., Wang, J. Rh-I-catalyzed Stille-type coupling of diazoesters with aryl trimethylstannanes Australian Journal of Chemistry  2015 68:1379-1384  DOI:10.1071/ch15218
    • Xia, Y., Xia, Y., Liu, Z., Zhang, Y., Wang, J. Palladium-catalyzed cross-coupling reaction of diazo compounds and vinyl boronic acids: an approach to 1,3-diene compounds Journal of Organic Chemistry  2014 79:7711-7717  DOI:10.1021/jo5012703  PMID:25019414
    • Xia, Y., Xia, Y., Ge, R., Liu, Z., Xiao, Q., Zhang, Y., Wang, J. Oxidative cross-coupling of allenyl ketones and organoboronic acids: expeditious synthesis of highly substituted furans Angewandte Chemie-International Edition  2014 53:3917-3921  DOI:10.1002/anie.201400500  PMID:24615951
    • Xia, Y., Liu, Z., Liu, Z., Ge, R., Ye, F., Hossain, M., Zhang, Y., Wang, J. Formal carbene insertion into C-C bond: Rh(I)-catalyzed reaction of benzocyclobutenols with diazoesters Journal of the American Chemical Society  2014 136:3013-3015  DOI:10.1021/ja500118w  PMID:24512084
    • Xia, Y., Qu, S., Xiao, Q., Wang, Z. X., Qu, P. Y., Chen, L., Liu, Z., Tian, L., Huang, Z., Zhang, Y., Wang, J. Palladium-catalyzed carbene migratory insertion using conjugated ene-yne-ketones as carbene precursors Journal of the American Chemical Society  2013 135:13502-13511  DOI:10.1021/ja4058844  PMID:23947689
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Background

education and training

  • Ph.D. in Chemistry, Scripps Research 2015 - 2019
  • B.S. in Chemistry, Peking University 2012 - 2015

advisee of

  • graduate advising relationship

    • Engle, Keary M., Ph.D.  candidacy, 2016 - 2019
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Contact

full name

  • Zhen Liu

geographic location

  • Scripps California 
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Identity

ORCID iD

  • ORCID iD http://orcid.org/0000-0002-1119-0693

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