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Knouse, Kyle
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Knouse, Kyle

Graduate Student
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Positions

  • 2013 - 2016 Undergraduate Research Assistant with Professor William Wuest, Temple University
  • 2015 Medicinal Chemistry Intern with Dr. Craig Zificsak, Teva Pharmaceuticals

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Publications

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  • 8

recent publications
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  • academic article

    • degree-related publication Knouse, K. W., Flood, D. T., Vantourout, J. C., Schmidt, M. A., McDonald, I. M., Eastgate, M. D., Baran, P. S. Nature Chose Phosphates and Chemists Should Too: How Emerging P(V) Methods Can Augment Existing Strategies ACS Central Science  2021 7:1473-1485  DOI:10.1021/acscentsci.1c00487  PMID:34584948  PMCID:PMC8461637
    • degree-related publication Huang, Y. Z., Knouse, K. W., Qiu, S. J., Hao, W., Padial, N. M., Vantourout, J. C., Zheng, B., Mercer, S. E., Lopez-Ogalla, J., Narayan, R., Olson, R. E., Blackmond, D. G., et al. A P(V) platform for oligonucleotide synthesis Science  2021 373:1265-1270  DOI:10.1126/science.abi9727  PMID:34516793
    • Flood, D. T., Hintzen, J. C. J., Knouse, K. W., Hill, D. E., Lu, C. X., Cistrone, P. A., Chen, J. S., Otomo, T., Dawson, P. Selenomethionine as an expressible handle for bioconjugations Proceedings of the National Academy of Sciences of the United States of America  2021 118  DOI:10.1073/pnas.2005164118  PMID:33602807  PMCID:PMC7923357
    • degree-related publication Ociepa, M., Knouse, K. W., He, D., Vantourout, J. C., Flood, D. T., Padial, N. M., Chen, J. S., Sanchez, B. B., Sturgell, E. J., Zheng, B., Qiu, S. J., Schmidt, M. A., et al. Mild and Chemoselective Phosphorylation of Alcohols Using a Psi-Reagent Organic Letters  2021 23:9337-9342  DOI:10.1021/acs.orglett.1c02736  PMID:34499517  PMCID:PMC8733960
    • degree-related publication Flood, D. T., Knouse, K. W., Vantourout, J. C., Kitamura, S., Sanchez, B. B., Sturgell, E. J., Chen, J. S., Wolan, D. W., Baran, P. S., Dawson, P. E. Synthetic Elaboration of Native DNA by RASS (SENDR) ACS Central Science  2020 6:1789-1799  DOI:10.1021/acscentsci.0c00680  PMID:33145415  PMCID:PMC7596865
    • degree-related publication Xu, D., Rivas-Bascon, N., Padial, N. M., Knouse, K. W., Zheng, B., Vantourout, J. C., Schmidt, M. A., Eastgate, M. D., Baran, P. S. Enantiodivergent Formation of C-P Bonds: Synthesis of P-Chiral Phosphines and Methylphosphonate Oligonucleotides Journal of the American Chemical Society  2020 142:5785-5792  DOI:10.1021/jacs.9b13898  PMID:32109356
    • degree-related publication Kawamata, Y., Vantourout, J. C., Hickey, D. P., Bai, P., Chen, L., Hou, Q., Qiao, W., Barman, K., Edwards, M. A., Garrido-Castro, A. F., DeGruyter, J. N., Nakamura, H., et al. Electrochemically driven, Ni-catalyzed aryl amination: scope, mechanism, and applications Journal of the American Chemical Society  2019 141:6392-6402  DOI:10.1021/jacs.9b01886  PMID:30905151
    • degree-related publication Knouse, K. W.*, deGruyter, J. N.*, Schmidt, M. A., Zheng, B., Vantourout, J. C., Kingston, C., Mercer, S. E., McDonald, I. M., Olson, R. E., Zhu, Y., Hang, C., Zhu, J., et al. Unlocking P(V): Reagents for chiral phosphorothioate synthesis Science  2018 361:1234-1238  DOI:10.1126/science.aau3369  PMID:30072577 (* = equal contribution)
    • degree-related publication Edwards, J. T., Merchant, R. R., McClymont, K. S., Knouse, K. W., Qin, T., Malins, L. R., Vokits, B., Shaw, S. A., Bao, D. H., Wei, F. L., Zhou, T., Eastgate, M. D., et al. Decarboxylative alkenylation Nature  2017 545:213-218  DOI:10.1038/nature22307  PMID:28424520
    • Knouse, K. W., Ator, L. E., Beausoleil, L. E., Hauseman, Z. J., Casaubon, R. L., Ott, G. R. Improved and expanded one-pot, two-component Boulton-Katritzky syntheses of N-N bond containing bicyclic heterocycles Tetrahedron Letters  2017 58:202-205  DOI:10.1016/j.tetlet.2016.11.092
    • Steele, A. D., Keohane, C. E., Knouse, K. W., Rossiter, S. E., Williams, S. J., Wuest, W. M. Diverted total synthesis of promysalin analogs demonstrates that an iron-binding motif is responsible for its narrow-spectrum antibacterial activity Journal of the American Chemical Society  2016 138:5833-5836  DOI:10.1021/jacs.6b03373  PMID:27096543  PMCID:PMC5084090
    • Knouse, K. W., Wuest, W. M. The enantioselective synthesis and biological evaluation of chimeric promysalin analogs facilitated by diverted total synthesis Journal of Antibiotics  2016 69:337-339  DOI:10.1038/ja.2016.4  PMID:26860469
    • He, L., Allwein, S. P., Dugan, B. J., Knouse, K. W., Ott, G. R., Zificsak, C. A. Synthesis of α-carboline Organic Syntheses  2016 93:272-285  DOI:10.15227/orgsyn.093.0272
    • Steele, A. D., Knouse, K. W., Keohane, C. E., Wuest, W. M. Total synthesis and biological investigation of (-)-promysalin Journal of the American Chemical Society  2015 137:7314-7317  DOI:10.1021/jacs.5b04767  PMID:26024439
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Background

education and training

  • Ph.D. in Chemistry, Scripps Research 2016 -
  • B.S. in Chemistry, Temple University 2011 - 2016

advisee of

  • graduate advising relationship

    • Baran, Phil, Ph.D.  candidacy, 2017 -
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Contact

full name

  • Kyle W. Knouse

geographic location

  • Scripps California 

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