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He, Jian

Graduate Student

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Positions

• 2016 - Postdoctoral Fellow, California Institute of Technology

Websites

• Doctoral Dissertation

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Publications

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• academic article

  • Shao, Q., Wu, Q. F., He, J., Yu, J. Q. Enantioselective γ-C(sp3)-H activation of alkyl amines via Pd(II)/Pd(0) catalysis Journal of the American Chemical Society  2018 140:5322-5325  DOI:10.1021/jacs.8b01094  PMID:29629766  PMCID:PMC5927623
  • He, J., Chen, C., Fu, G. C., Peters, J. C. Visible-light-induced, copper-catalyzed three-component coupling of alkyl halides, olefins, and trifluoromethylthiolate to generate trifluoromethyl thioethers ACS Catalysis  2018 8:11741-11748  DOI:10.1021/acscatal.8b04094
  • Pei, Q. L., Che, G. D., Zhu, R. Y., He, J., Yu, J. Q. An epoxide-mediated deprotection method for acidic amide auxiliary Organic Letters  2017 19:5860-5863  DOI:10.1021/acs.orglett.7b02841  PMID:29039962
  • Wu, Q. F., Shen, P. X., He, J., Wang, X. B., Zhang, F., Shao, Q., Zhu, R. Y., Mapelli, C., Qiao, J. X., Poss, M. A., Yu, J. Q. Formation of α-chiral centers by asymmetric β-C(sp(3))-H arylation, alkenylation, and alkynylation Science  2017 355:499-503  DOI:10.1126/science.aal5175  PMID:28154075
  • Zhu, R. Y., Saint-Denis, T. G., Shao, Y., He, J., Sieber, J. D., Senanayake, C. H., Yu, J. Q. Ligand-enabled Pd(II)-catalyzed bromination and iodination of C(sp3)-H bonds Journal of the American Chemical Society  2017 139:5724-5727  DOI:10.1021/jacs.7b02196  PMID:28391681
  • Fu, H., Shen, P. X., He, J., Zhang, F., Li, S., Wang, P., Liu, T., Yu, J. Q. Ligand-enabled alkynylation of C(sp3 )-H bonds with palladium(II) catalysts Angewandte Chemie-International Edition  2017 56:1873-1876  DOI:10.1002/anie.201610426  PMID:28078773
  • Wang, H. W., Lu, Y., Zhang, B., He, J., Xu, H. J., Kang, Y. S., Sun, W. Y., Yu, J. Q. Ligand-promoted rhodium(III)-catalyzed ortho-C-H amination with free amines Angewandte Chemie-International Edition  2017 56:7449-7453  DOI:10.1002/anie.201703300  PMID:28500664
  • He, J., Wasa, M., Chan, K. S. L., Shao, O., Yu, J. Q. Palladium-catalyzed transformations of alkyl C-H bonds Chemical Reviews  2017 117:8754-8786  DOI:10.1021/acs.chemrev.6b00622  PMID:28697604  PMCID:PMC5516964
  • He, J., Shao, Q., Wu, Q., Yu, J. Q. Pd(II)-catalyzed enantioselective C(sp(3))-H borylation Journal of the American Chemical Society  2017 139:3344-3347  DOI:10.1021/jacs.6b13389  PMID:28209055
  • Hoyt, C. B., Lee, L. C., He, J., Yu, J. Q., Jones, C. W. Selective C(sp(3))-H monoarylation catalyzed by a covalently cross-linked reverse micelle-supported palladium catalyst Advanced Synthesis & Catalysis  2017 359:3611-3617  DOI:10.1002/adsc.201700707
  • Lee, L. C., He, J., Yu, J. Q., Jones, C. W. Functionalized polymer-supported pyridine ligands for palladium-catalyzed C(sp(3))-H arylation ACS Catalysis  2016 6:5245-5250  DOI:10.1021/acscatal.6b01774
  • Jiang, H., He, J., Liu, T., Yu, J. Q. Ligand-enabled γ-C(sp(3))-H olefination of amines: en route to pyrrolidines Journal of the American Chemical Society  2016 138:2055-2059  DOI:10.1021/jacs.5b13462  PMID:26796676  PMCID:PMC4817546
  • He, J., Jiang, H., Takise, R., Zhu, R. Y., Chen, G., Dai, H. X., Dhar, T. G. M., Shi, J., Zhang, H., Cheng, P. T. W., Yu, J. Q. Ligand-promoted borylation of C(sp(3))-H bonds with palladium(II) catalysts Angewandte Chemie-International Edition  2016 55:785  DOI:10.1002/anie.201509996  PMID:26611496  PMCID:PMC4821169
  • Wang, P., Li, G. C., Jain, P., Farmer, M. E., He, J., Shen, P. X., Yu, J. Q. Ligand-promoted meta-C-H amination and alkynylation Journal of the American Chemical Society  2016 138:14092-14099  DOI:10.1021/jacs.6b08942  PMID:27712063
  • He, J., Takise, R., Fu, H., Yu, J. Q. Ligand-enabled cross-coupling of C(sp(3))-H bonds with arylsilanes Journal of the American Chemical Society  2015 137:4618-4621  DOI:10.1021/jacs.5b00890  PMID:25822198  PMCID:PMC4432906
  • Zhu, R. Y., Tanaka, K., Li, G. C., He, J., Fu, H. Y., Li, S. H., Yu, J. Q. Ligand-enabled stereoselective β-C(sp(3))-H fluorination: Synthesis of unnatural enantiopure anti-β-fluoro-α-amino acids Journal of the American Chemical Society  2015 137:7067-7070  DOI:10.1021/jacs.5b04088  PMID:26001406  PMCID:PMC4934178
  • Chen, G., Shigenari, T., Jain, P., Zhang, Z., Jin, Z., He, J., Li, S., Mapelli, C., Miller, M. M., Poss, M. A., Scola, P. M., Yeung, K. S., et al. Ligand-enabled β-C-H arylation of α-amino acids using a simple and practical auxiliary Journal of the American Chemical Society  2015 137:3338-3351  DOI:10.1021/ja512690x  PMID:25697780  PMCID:PMC4432912
  • Zhu, D., Yang, G., He, J., Chu, L., Chen, G., Gong, W., Chen, K., Eastgate, M. D., Yu, J. Q. Ligand-promoted ortho-C-H amination with Pd catalysts Angewandte Chemie-International Edition  2015 54:2497-2500  DOI:10.1002/anie.201408651  PMID:25598232
  • He, J., Shigenari, T., Yu, J. Q. Palladium(0)/PAr3-catalyzed intermolecular amination of C(sp3)[BOND]H bonds: Synthesis of ß-amino acids Angewandte Chemie-International Edition  2015 54:6545-6549  DOI:10.1002/anie.201502075  PMID:25873526
  • He, J., Li, S., Deng, Y., Fu, H., Laforteza, B. N., Spangler, J. E., Homs, A., Yu, J. Q. Ligand-controlled C(sp(3))-H arylation and olefination in synthesis of unnatural chiral alpha-amino acids Science  2014 343:1216-1220  DOI:10.1126/science.1249198  PMID:24626923  PMCID:PMC4179246
  • Deng, Y., Gong, W., He, J., Yu, J. Q. Ligand-enabled triple C-H activation reactions: one-pot synthesis of diverse 4-aryl-2-quinolinones from propionamides Angewandte Chemie-International Edition  2014 53:6692-6695  DOI:10.1002/anie.201403878  PMID:24828691  PMCID:PMC4114037
  • Zhu, R. Y., He, J., Wang, X. C., Yu, J. Q. Ligand-promoted alkylation of C(sp(3))-H and C(sp(2))-H bonds Journal of the American Chemical Society  2014 136:13194-13197  DOI:10.1021/ja508165a  PMID:25208210  PMCID:PMC4183600
  • He, J., Wasa, M., Chan, K. S. L., Yu, J. Q. Palladium(0)-catalyzed alkynylation of C(sp3)-H bonds Journal of the American Chemical Society  2013 135:3387-3390  DOI:10.1021/ja400648w  PMID:23406445
  • He, J., Lu, Z., Chai, G., Fu, C., Ma, S. CuCl-catalyzed stereoselective conjugate addition of Grignard reagents to 2,3-allenoates Tetrahedron  2012 68:2719-2724  DOI:10.1016/j.tet.2012.01.027
  • Wasa, M., Chan, K. S. L., Zhang, X. G., He, J., Miura, M., Yu, J. Q. Ligand-enabled methylene C(sp3)-H bond activation with a Pd(II) catalyst Journal of the American Chemical Society  2012 134:18570-18572  DOI:10.1021/ja309325e  PMID:23116159  PMCID:PMC3500088

Background

education and training

• Ph.D. in Chemistry, Scripps Research 2011 - 2016
• B.S. in Chemistry, Zhejiang University 2007 - 2011

advisee of

• graduate advising relationship

  • Yu, Jin-Quan, Ph.D.  candidacy, 2012 - 2016

Contact

full name

• Jian He

geographic location

• Scripps California