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He, Jian
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He, Jian

Graduate Student
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Positions

  • 2016 - Postdoctoral Fellow, California Institute of Technology

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Publications

recent publications
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  • academic article

    • He, J., Chen, C., Fu, G. C., Peters, J. C. Visible-light-induced, copper-catalyzed three-component coupling of alkyl halides, olefins, and trifluoromethylthiolate to generate trifluoromethyl thioethers ACS Catalysis  2018 8:11741-11748  DOI:10.1021/acscatal.8b04094
    • degree-related publication Shao, Q., Wu, Q. F., He, J., Yu, J. Q. Enantioselective γ-C(sp3)-H activation of alkyl amines via Pd(II)/Pd(0) catalysis Journal of the American Chemical Society  2018 140:5322-5325  DOI:10.1021/jacs.8b01094  PMID:29629766  PMCID:PMC5927623
    • degree-related publication Pei, Q. L., Che, G. D., Zhu, R. Y., He, J., Yu, J. Q. An epoxide-mediated deprotection method for acidic amide auxiliary Organic Letters  2017 19:5860-5863  DOI:10.1021/acs.orglett.7b02841  PMID:29039962
    • degree-related publication Hoyt, C. B., Lee, L. C., He, J., Yu, J. Q., Jones, C. W. Selective C(sp(3))-H monoarylation catalyzed by a covalently cross-linked reverse micelle-supported palladium catalyst Advanced Synthesis & Catalysis  2017 359:3611-3617  DOI:10.1002/adsc.201700707
    • degree-related publication He, J., Wasa, M., Chan, K. S. L., Shao, O., Yu, J. Q. Palladium-catalyzed transformations of alkyl C-H bonds Chemical Reviews  2017 117:8754-8786  DOI:10.1021/acs.chemrev.6b00622  PMID:28697604  PMCID:PMC5516964
    • degree-related publication Wang, H. W., Lu, Y., Zhang, B., He, J., Xu, H. J., Kang, Y. S., Sun, W. Y., Yu, J. Q. Ligand-promoted rhodium(III)-catalyzed ortho-C-H amination with free amines Angewandte Chemie-International Edition  2017 56:7449-7453  DOI:10.1002/anie.201703300  PMID:28500664
    • degree-related publication Zhu, R. Y., Saint-Denis, T. G., Shao, Y., He, J., Sieber, J. D., Senanayake, C. H., Yu, J. Q. Ligand-enabled Pd(II)-catalyzed bromination and iodination of C(sp3)-H bonds Journal of the American Chemical Society  2017 139:5724-5727  DOI:10.1021/jacs.7b02196  PMID:28391681
    • degree-related publication He, J., Shao, Q., Wu, Q., Yu, J. Q. Pd(II)-catalyzed enantioselective C(sp(3))-H borylation Journal of the American Chemical Society  2017 139:3344-3347  DOI:10.1021/jacs.6b13389  PMID:28209055
    • degree-related publication Fu, H., Shen, P. X., He, J., Zhang, F., Li, S., Wang, P., Liu, T., Yu, J. Q. Ligand-enabled alkynylation of C(sp3 )-H bonds with palladium(II) catalysts Angewandte Chemie-International Edition  2017 56:1873-1876  DOI:10.1002/anie.201610426  PMID:28078773
    • degree-related publication Wu, Q. F., Shen, P. X., He, J., Wang, X. B., Zhang, F., Shao, Q., Zhu, R. Y., Mapelli, C., Qiao, J. X., Poss, M. A., Yu, J. Q. Formation of α-chiral centers by asymmetric β-C(sp(3))-H arylation, alkenylation, and alkynylation Science  2017 355:499-503  DOI:10.1126/science.aal5175  PMID:28154075
    • degree-related publication Wang, P., Li, G. C., Jain, P., Farmer, M. E., He, J., Shen, P. X., Yu, J. Q. Ligand-promoted meta-C-H amination and alkynylation Journal of the American Chemical Society  2016 138:14092-14099  DOI:10.1021/jacs.6b08942  PMID:27712063
    • degree-related publication Lee, L. C., He, J., Yu, J. Q., Jones, C. W. Functionalized polymer-supported pyridine ligands for palladium-catalyzed C(sp(3))-H arylation ACS Catalysis  2016 6:5245-5250  DOI:10.1021/acscatal.6b01774
    • degree-related publication Jiang, H., He, J., Liu, T., Yu, J. Q. Ligand-enabled γ-C(sp(3))-H olefination of amines: en route to pyrrolidines Journal of the American Chemical Society  2016 138:2055-2059  DOI:10.1021/jacs.5b13462  PMID:26796676  PMCID:PMC4817546
    • degree-related publication He, J., Jiang, H., Takise, R., Zhu, R. Y., Chen, G., Dai, H. X., Dhar, T. G. M., Shi, J., Zhang, H., Cheng, P. T. W., Yu, J. Q. Ligand-promoted borylation of C(sp(3))-H bonds with palladium(II) catalysts Angewandte Chemie-International Edition  2016 55:785  DOI:10.1002/anie.201509996  PMID:26611496  PMCID:PMC4821169
    • degree-related publication Zhu, R. Y., Tanaka, K., Li, G. C., He, J., Fu, H. Y., Li, S. H., Yu, J. Q. Ligand-enabled stereoselective β-C(sp(3))-H fluorination: Synthesis of unnatural enantiopure anti-β-fluoro-α-amino acids Journal of the American Chemical Society  2015 137:7067-7070  DOI:10.1021/jacs.5b04088  PMID:26001406  PMCID:PMC4934178
    • degree-related publication He, J., Shigenari, T., Yu, J. Q. Palladium(0)/PAr3-catalyzed intermolecular amination of C(sp3)[BOND]H bonds: Synthesis of ß-amino acids Angewandte Chemie-International Edition  2015 54:6545-6549  DOI:10.1002/anie.201502075  PMID:25873526
    • degree-related publication He, J., Takise, R., Fu, H., Yu, J. Q. Ligand-enabled cross-coupling of C(sp(3))-H bonds with arylsilanes Journal of the American Chemical Society  2015 137:4618-4621  DOI:10.1021/jacs.5b00890  PMID:25822198  PMCID:PMC4432906
    • degree-related publication Chen, G., Shigenari, T., Jain, P., Zhang, Z., Jin, Z., He, J., Li, S., Mapelli, C., Miller, M. M., Poss, M. A., Scola, P. M., Yeung, K. S., et al. Ligand-enabled β-C-H arylation of α-amino acids using a simple and practical auxiliary Journal of the American Chemical Society  2015 137:3338-3351  DOI:10.1021/ja512690x  PMID:25697780  PMCID:PMC4432912
    • degree-related publication Zhu, D., Yang, G., He, J., Chu, L., Chen, G., Gong, W., Chen, K., Eastgate, M. D., Yu, J. Q. Ligand-promoted ortho-C-H amination with Pd catalysts Angewandte Chemie-International Edition  2015 54:2497-2500  DOI:10.1002/anie.201408651  PMID:25598232
    • degree-related publication Zhu, R. Y., He, J., Wang, X. C., Yu, J. Q. Ligand-promoted alkylation of C(sp(3))-H and C(sp(2))-H bonds Journal of the American Chemical Society  2014 136:13194-13197  DOI:10.1021/ja508165a  PMID:25208210  PMCID:PMC4183600
    • degree-related publication Deng, Y., Gong, W., He, J., Yu, J. Q. Ligand-enabled triple C-H activation reactions: one-pot synthesis of diverse 4-aryl-2-quinolinones from propionamides Angewandte Chemie-International Edition  2014 53:6692-6695  DOI:10.1002/anie.201403878  PMID:24828691  PMCID:PMC4114037
    • degree-related publication He, J., Li, S., Deng, Y., Fu, H., Laforteza, B. N., Spangler, J. E., Homs, A., Yu, J. Q. Ligand-controlled C(sp(3))-H arylation and olefination in synthesis of unnatural chiral alpha-amino acids Science  2014 343:1216-1220  DOI:10.1126/science.1249198  PMID:24626923  PMCID:PMC4179246
    • degree-related publication He, J., Wasa, M., Chan, K. S. L., Yu, J. Q. Palladium(0)-catalyzed alkynylation of C(sp3)-H bonds Journal of the American Chemical Society  2013 135:3387-3390  DOI:10.1021/ja400648w  PMID:23406445
    • degree-related publication Wasa, M., Chan, K. S. L., Zhang, X. G., He, J., Miura, M., Yu, J. Q. Ligand-enabled methylene C(sp3)-H bond activation with a Pd(II) catalyst Journal of the American Chemical Society  2012 134:18570-18572  DOI:10.1021/ja309325e  PMID:23116159  PMCID:PMC3500088
    • He, J., Lu, Z., Chai, G., Fu, C., Ma, S. CuCl-catalyzed stereoselective conjugate addition of Grignard reagents to 2,3-allenoates Tetrahedron  2012 68:2719-2724  DOI:10.1016/j.tet.2012.01.027
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Background

education and training

  • Ph.D. in Chemistry, Scripps Research 2011 - 2016
  • B.S. in Chemistry, Zhejiang University 2007 - 2011

advisee of

  • graduate advising relationship

    • Yu, Jin-Quan, Ph.D.  candidacy, 2012 - 2016
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Contact

full name

  • Jian He

geographic location

  • Scripps California 

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