recent publications
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academic article
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Derosa, J., Apolinar, O., Kang, T., Tran, V. T., Engle, K. M. Recent developments in nickel-catalyzed intermolecular dicarbofunctionalization of alkenes Chemical Science 2020 11:4287-4296 DOI:10.1039/c9sc06006e
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Tran, V. T., Li, Z. Q., Apolinar, O., Derosa, J., Joannou, M. V., Wisniewski, S. R., Eastgate, M. D., Engle, K. M. Ni(COD)(DQ): An air-stable 18-electron nickel(0)-olefin precatalyst Angewandte Chemie-International Edition 2020 DOI:10.1002/anie.202000124 PMID:32065839
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Tran, V. T., Li, Z. Q., Gallagher, T. J., Derosa, J., Liu, P., Engle, K. M. Integrating allyl electrophiles into nickel-catalyzed conjunctive cross-coupling Angewandte Chemie-International Edition 2020 59:7029-7034 DOI:10.1002/anie.201915454 PMID:31958202 PMCID:PMC7184930
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Derosa, J.*, Kang, T.*, Tran, V., Wisniewski, S. R., Karunananda, M. K., Jankins, T. C., Xu, K. L., Engle, K. M. Nickel-catalyzed 1,2-diarylation of alkenyl carboxylates: a gateway to 1,2,3-trifunctionalized building blocks Angewandte Chemie-International Edition 2020 1201-1205 DOI:10.1002/anie.201913062 PMID:31693286 (* = equal contribution)
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Medina, J. M., Kang, T., Erbay, T. G., Shao, H., Gallego, G. M., Yang, S., Tran-Dube, M., Richardson, P. F., Derosa, J., Helsel, R. T., Patman, R. L., Wang, F., et al. Cu-catalyzed hydroboration of benzylidenecyclopropanes: reaction optimization, (hetero)aryl scope, and origins of pathway selectivity ACS Catalysis 2019 9:11130-11136 DOI:10.1021/acscatal.9b03557
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Van Der Puyl, V. A., Derosa, J., Engle, K. M. Directed, nickel-catalyzed umpolung 1,2-carboamination of alkenyl carbonyl compounds ACS Catalysis 2019 9:224-229 DOI:10.1021/acscatal.8b04516
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Derosa, J., Kleinmans, R., Tran, V. T., Karunananda, M. K., Wisniewski, S. R., Eastgate, M. D., Engle, K. M. Nickel-catalyzed 1,2-diarylation of simple alkenyl amides Journal of the American Chemical Society 2018 140:17878-17883 DOI:10.1021/jacs.8b11942 PMID:30525575
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Derosa, J., van der Puyl, V. A., Tran, V. T., Liu, M., Engle, K. M. Directed nickel-catalyzed 1,2-dialkylation of alkenyl carbonyl compounds Chemical Science 2018 9:5278-5283 DOI:10.1039/c8sc01735b
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Derosa, J., O'Duill, M. L., Holcomb, M., Boulous, M. N., Patman, R. L., Wang, F., Tran-Dube, M., McAlpine, I., Engle, K. M. Copper-catalyzed Chan-Lam cyclopropylation of phenols and azaheterocycles Journal of Organic Chemistry 2018 83:3417-3425 DOI:10.1021/acs.joc.7b03100 PMID:29498847
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Derosa, J., Tran, V. T., van der Puyl, V. A., Engle, K. M. Carbon-carbon pi bonds as conjunctive reagents in cross-coupling Aldrichimica Acta 2018 51:21-32
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Derosa, J.*, Tran, V. T.*, Boulous, M. N., Chen, J. S., Engle, K. M. Nickel-catalyzed β,γ-dicarbofunctionalization of alkenyl carbonyl compounds via conjunctive cross-coupling Journal of the American Chemical Society 2017 139:10657-10660 DOI:10.1021/jacs.7b06567 PMID:28738150 (* = equal contribution)
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Derosa, J., Cantu, A. L., Boulous, M. N., O'Duill, M. L., Turnbull, J. L., Liu, Z., De La Torre, D. M., Engle, K. M. Palladium(II)-catalyzed directed anti-hydrochlorination of unactivated alkynes with HCl Journal of the American Chemical Society 2017 139:5183-5193 DOI:10.1021/jacs.7b00892 PMID:28266849
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Liu, Z., Derosa, J., Engle, K. M. Palladium(II)-catalyzed regioselective syn-hydroarylation of disubstituted alkynes using a removable directing group Journal of the American Chemical Society 2016 138:13076-13081 DOI:10.1021/jacs.6b08818 PMID:27602748
- Wang, C. Y., Derosa, J., Biscoe, M. R. Configurationally stable, enantioenriched organometallic nucleophiles in stereospecific Pd-catalyzed cross-coupling reactions: an alternative approach to asymmetric synthesis Chemical Science 2015 6:5105-5113 DOI:10.1039/c5sc01710f PMID:26388985 PMCID:PMC4571484
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